有机金属化学与催化
课程编码：180082070303P0001H
英文名称：Organometallic Chemistry & Catalysis
课时：20
学分：1.00
课程属性：高级强化课
主讲教师：Gregory Solan等
教学目的要求
To introduce Organometallic catalaysis and its use in Catalysis/介绍有机金属催化及其在催化中的应用
预修课程
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大纲内容
第一章 Metal-Carbonyl Chemistry 4.0学时 Gregory Solan
第1节 Intro to OM Chemistry
第2节 I8 e- rule, preparation of binary metal carbonyl complexes
第3节 Bonding of a CO to a TM and phosphines (PR3)
第4节 Reactions of transition metal carbonyls
第二章 Metal-hydride Chemistry 2.0学时 Gregory Solan
第1节 TM hydrides
第2节 TM hydrides: preparation, acidity and detecting the hydride
第三章 Metal-alkyl chemistry 3.0学时 Gregory Solan
第1节 Metal-alkyl complexes
第2节 Preparation of TM- and MG-alkyl complexes
第3节 Reactions of TM-alkyl complexes
第四章 Transition metal-carbon p-bonds 4.0学时 Gregory Solan
第1节 TM-carbon p-bonds; metal alkene complexes
第2节 Transition metal-carbon p-bonds; metal-alkene and metal-alkyne complexes
第3节 Transition metal-carbon p-bonds; metal-allyl complexes
第4节 TM-carbon p-bonds; metal-cyclopentadienyl, metal-arene complexes
第五章 Catalysis 5.0学时 Gregory Solan
第1节 INTRO TO CATALYSIS
第2节 HYDROGENATION/HYDROFORMYLATION
第3节 ACETIC ACID
第4节 OLEFIN OLIGOMERIZATION
第5节 OLEFIN POLYMERIZATION
第六章 Written test 2.0学时 Gregory Solan
第1节 Written test (assessment)
第2节 Written test (assessment)
教材信息
1、
1. Organometallics 1, 2. Organometallics 2, 3. Applied Organometallic Chemistry and Catalysis
1. Manfred Bochmann, 2. Manfred Bochmann, 3.Robin Whyman
1. April 1994, 2. April 1994, 3. September 2001
Oxford University Primer
参考书
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课程教师信息
1. Fellow of the Higher Education Academy in the UK since 2016.
2. University Teaching Experience: Lecturer and Tutor for core Coordination Chemistry module for L1 UGs (University of Leicester & Dalian Leicester Institute); Module lead, Lecturer and Tutor for core Organometallic Chemistry module for L2 UGs; Module lead, Lecturer and Tutor for core Advanced Inorganic Chemistry module for L3 UGs; Module lead for L3 Advanced Inorganic Practical course for UGs; Module lead for L3 BSc research projects for UGs; Lecturer and tutor for optional modules for L4 UGs (e.g., Cluster Chemistry, Metal-Ligand Multiple bonds); ‘Premier’ teaching assistant for Inorganic Chemistry laboratory course (Lausanne); Supervision of L3/L4 project students (Leicester, Imperial College, Edinburgh, Lausanne, Cambridge).