金属有机化学与催化

课程编码：1801010703I0P1001Y 英文名称：Organometallic Chemistry and Catalysis 课时：50 学分：2.50 课程属性：学科核心课 主讲教师：孙文华等

Chemistry is the center of sciences, and organometallic chemistry is the useful tool for chemists to understand how organic molecules or groups interact with compounds of the inorganic elements. On the base of Organometallic Chemistry, the industries of chemical, petrochemical, pharmacy and organic materials have been continuously developing. A catalyst increases the rate of a reaction without being consumed and without changing the thermodynamics of the reaction, providing bases for modern chemical industries. With regard to Periodic Table of Elements, main group elements consisting of the s and p blocks and the transition elements of the d and f blocks would be discussed, respectively. Those organometallic compounds have been useful building blocks for nanoparticles and assembling materials. Importantly, organometallic compounds have been stoichiometric reagents and (pre)catalysts in tremendously industrial processes. Therefore organometallic chemistry and catalysis are the Capital Stone for scientists in chemistry, material science and industry.

General chemistry

第一章 Definition & Scope of Organometallic chemistry 6.0学时 孙文华
第1节 Definition & Scope of Organometallic chemistry
第2节 Coordination chemistry: from complex to coordination by Nobel Laureate Werner
第二章 Organometallics of Main Metals 12.0学时 孙文华
第1节 Alkali Metal Organometallics
Alkaline Earth Metal Organometallics
第2节 Zinc, Cadmium, and Mercury Organometallics: properties and applications
第3节 Organometallics of the Boron Group
第4节 Organometallics of the Carbon Group
第三章 Special topic on application of Organometallics 3.0学时 孙文华
第1节 Oxidative coupling of unsaturated substrates based on the Reaction Chemistry of Zirconocene Complexes
第四章 Organometallics of Transition Metals 18.0学时 孙文华
第1节 Organometallics of Transition Metals
第2节 Metal Hydrides; Bonding in metal hydrides; Preparation of TM carbonyl hydrides; General points about oxidative addition
第3节 Metal-Alkyl Complexe
第4节 Metal alkene (olefin) complexes: bonding, preparation, and reactions
Metal alkyne complexes: bonding, preparation, and reactions
Their applications
第5节 TRANSITION METAL-CARBON MULTIPLE BONDS
第6节 Basics of Organometallics; Historical Background in Organometallics; Charges and corresponding coordination numbers for typical ligands
第五章 CATALYSIS 9.0学时 孙文华
第1节 CATALYSIS
INTRODUCTION AND DESCRIPTIONS
第2节 CO ETHYLENE COPOLYMERISATION
第3节 OLEFIN POLYMERISATION;
RING OPENING POLYMERISATION
第六章 Final test 2.0学时 孙文华
第1节 Final test

Prof. Sun Wen-Hua et al.