课程大纲

课程大纲

金属有机化学

课程编码:0703I0M01001H 英文名称:Organometallic Chemistry 课时:50 学分:3.00 课程属性:一级学科核心课 主讲教师:孙文华等

教学目的要求
Chemistry is the center of sciences, and organometallic chemistry is the useful tool for chemists to understand how organic molecules or groups interact with compounds of the inorganic elements. On the base of Organometallic Chemistry, the industries of chemical, petrochemical, pharmacy and organic materials have been continuously developing. A catalyst increases the rate of a reaction without being consumed and without changing the thermodynamics of the reaction, providing bases for modern chemical industries. With regard to Periodic Table of Elements, main group elements consisting of the s and p blocks and the transition elements of the d and f blocks would be discussed, respectively. Those organometallic compounds have been useful building blocks for nanoparticles and assembling materials. Importantly, organometallic compounds have been stoichiometric reagents and (pre)catalysts in tremendously industrial processes. Therefore organometallic chemistry and catalysis are the Capital Stone for scientists in chemistry, material science and industry.

预修课程
General chemistry

大纲内容
第一章 Definition & Scope of Organometallic chemistry 6学时 孙文华
第1节 Definition & Scope of Organometallic chemistry;Interests in OM chemistry
18 electron rule and in OM
第2节 Coordination chemistry: from complex to coordination by Nobel Laureate Werner Coordination Number, ligand Number and Dentate Number
第二章 Organometallics of Main Metals 12学时 孙文华
第1节 Alkali Metal Organometallics: Li, Na, K, Rb, Cs; preparation, reactivity and structures
第2节 Zinc, Cadmium, and Mercury Organometallics: properties and applications
第3节 Organometallics of the Boron Group: Transmetallation, reactions and uncommon bonding Aluminium organometallics: Cyclopentadienylaluminium, reactivity, structures
第4节 Organometallics of the Carbon Group: Synthesis, reactivity, bondings Compounds of Low-valent Silicon: Silyl Anions, Cyclosilanes, Silicocene, Silylenes, Silyl radicals and silyl cations
第三章 Special topic on application of Organometallics 3学时 孙文华
第1节 Oxidative coupling of unsaturated substrates based on the Reaction Chemistry of Zirconocene Complexes\
第四章 Organometallics of Transition Metals 18学时 孙文华
第1节 Semi-test
第2节 Metal Hydrides; Bonding in metal hydrides
第3节 Metal-Alkyl Complexes
第4节 Metal alkene(olefin)complexes
第5节 TRANSITION METAL-CARBON MULTIPLE BONDS
第6节 Coordination & Dissociation
第五章 CATALYSIS 9学时 孙文华
第1节 CATALYSIS
INTRODUCTION AND DESCRIPTIONS
第2节 CO ETHYLENE COPOLYMERISATION
第3节 OLEFIN POLYMERISATION;
RING OPENING POLYMERISATION
第六章 Final test 2学时 孙文华
第1节 Final test

参考书
1、

课程教师信息
Prof. Sun Wen-Hua